Synthesis, structure and properties of V(V) monooxido complex with ONO tridentate Schiff base

Autor

DOI:

https://doi.org/10.5604/01.3001.0013.1046

Słowa kluczowe:

vanadium, complex, Schiff base, structure, 5-methoxysalicylaldehyde, phenylacetic hydrazide

Abstrakt

The oxidovanadium(V) Schiff base complex of formula [VO(L)(EtO)(EtOH)] (where H2L = Schiff base ligand derived from 5-methoxysalicylaldehyde and phenylacetic hydrazide) was synthesized and described. Complex crystalizes in triclinic P-1 space group. Octahedral geometry of the vanadium(V) centre is filed with oxido, ONO L2- ligand and two solvent molecules both in ethoxo and as neutral ethanol form. The complex is neutral, with 5- and 6-memebered ring formed by ONO ligand coordinated in octahedral plane with oxido and EtOH ligands in vertical positions. Two isomers are present in the unit cell, with different position of 5-membered ring versus vertical plane. The elemental analysis, magnetic susceptibility, thermogravimetry and spectroscopy (IR, UV-Vis) measurements were measured and are discussed. The cyclic voltammetry measurements show irreversible processes for vanadium(IV/V) redox system. Thermal stability both in a solid state (TG and SDTA measurements) as well as in solutions (at pH 7.0 and 2.0, studied by UV-Vis spectroscopy) is discussed.

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The hydrogen bonds in 1

Opublikowane

2019-03-14

Jak cytować

Jurowska, A., Szklarzewicz, J., Hodorowicz, M., & Gryboś, R. (2019). Synthesis, structure and properties of V(V) monooxido complex with ONO tridentate Schiff base. Science, Technology and Innovation, 4(1), 21–29. https://doi.org/10.5604/01.3001.0013.1046

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