Wgląd w termodynamikę procesu adsorpcji siarkowodoru poprzez wielotemperaturowy opis związanych z nim izoterm
DOI:
https://doi.org/10.55225/sti.706Słowa kluczowe:
siarkowodór, adsorpcja, termodynamika, model kooperatywnej sorpcji wielocząsteczkowej, opis wielotemperaturowyAbstrakt
Adsorpcja siarkowodoru jest procesem o znaczeniu praktycznym, m.in. w kontekście odsiarczania biogazu. Jego pełne zrozumienie może wymagać poznania związanych z nim aspektów termodynamicznych. Niniejsza praca dotyczy sprawdzenia możliwości pośredniego uzyskania danych tego rodzaju w oparciu o modelowanie matematyczne zmienności temperaturowej izoterm adsorpcji H₂S. W tym celu jako równanie izotermy teoretycznej wybrano model kooperatywnej sorpcji wielocząsteczkowej i wykorzystano go do jednoczesnego opisu wielotemperaturowego kilku zestawów danych doświadczalnych. Takie podejście, pomimo pewnych ograniczeń, jest skutecznym narzędziem modelowania adsorpcji siarkowodoru na badanych węglach aktywnych i zeolitach. Umożliwia ponadto wygenerowanie w prosty sposób wielkości termodynamicznych charakteryzujących proces: izosterycznej entalpii adsorpcji oraz entropii fazy zaadsorbowanej. W pracy z powodzeniem wyznaczono i przeanalizowano krzywe obrazujące zmiany tych funkcji wraz z postępem adsorpcji, które uzupełniają charakterystyki ilościowe tego procesu.
Statystyka pobrań
Bibliografia
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Prawa autorskie (c) 2026 Sylwester Furmaniak, Piotr A. Gauden
Utwór dostępny jest na licencji Creative Commons Uznanie autorstwa – Na tych samych warunkach 4.0 Miedzynarodowe.
